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Potential-pH Diagrams
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TUTORIAL ON THERMEXPERTTM Potential-pH (Pourbaix or EMF-pH) Diagram Generator
David C. Silverman
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Table of Contents
THERMEXPERT-generating web-based potential-pH diagrams
THERMEXPERT
or the internet-based, potential-pH diagram generator has been created as to
provide a straightforward way of calculating potential-pH or Pourbaix diagrams on
the internet. The web application gives the user the flexibility to choose the
temperature and ionic activities (concentrations). This web-based application
has its own thermodynamic data data base developed with an eye toward internal consistency.
Such a data base relieves the user from having to develop such information.
This tutorial has been developed to provide appropriate background for using
THERMEXPERT for calculating potential-pH diagrams for systems encountered in practice.
The user is not limited to the interaction of metals and inorganic ions.
The thermodynamics of organic complexing agents interacting with the metal can also be
examined. In this vein, please contact
Argentum Solutions if a desired interacting species or metal
is not present. It can be added to the thermodynamic data base.
Reading this tutorial in its entirety is suggested for those who need additional
background on the generation and use of potential-pH diagrams for corrosion prediction. For
those who have sufficient background, reading the section entitled
Using THERMEXPERT - a step-by-step procedure
will provide the background needed for using this application successfully. Users are urged to read this
section prior to generating potential-pH diagrams with THERMEXPERT.
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Previous Page: Case Study-Complexing Agents-Iron/iminodiacetic acid
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1 © NACE International publication and year shown in citation above. All rights reserved. Displayed with permission from NACE International, Houston, TX (http://www.nace.org). Published in Corrosion, in the month and year shown in the citation above.
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David C. Silverman, Ph.D. - Primary Consultant
E-Mail: dcsilverman@argentumsolutions.com
Phone: 314-576-3586
Fax: 314-754-9825
Address: The Argentum House
14314 Strawbridge Ct.
Chesterfield, MO 63017
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