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2008 Frank Newman Speller Award Lecture
Practical prediction and evaluation of velocity sensitive corrosion
Practical and rapid corrosion prediction using Electrochemical Impedance Spectroscopy
Practical and rapid corrosion prediction using DC electrochemical techniques
Practical Applications of Artificial Neural Networks and Expert Systems to Corrosion
Practical corrosion prediction in chemical plant waste streams
Enhanced prediction of performance of elastomers and other non-metallic materials
Corrosion inhibitor development and evaluation
Advanced coating system development and evaluation/Conducting polymers
Practical corrosion prediction using potential-pH diagrams
Other publications on prediction of uniform and localized corrosion
2008 Frank Newman Speller Award Lecture
- D. C. Silverman, "Developing and Applying Technologies - Practical Corrosion Prediction", Corrosion, Vol. 64, No. 8, p. 627 (2008).1
 (5500k)
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Practical prediction and evaluation of velocity sensitive corrosion
- D. C. Silverman, "Rotating Cylinder Electrode For Velocity Sensitivity Testing", Corrosion, Vol. 40, No. 5, p. 220 (1984).1 (466k)
- D. C. Silverman and M. E. Zerr, "Application Of Rotating Cylinder Electrode --
E-Brite 26-1/ Concentrated Sulfuric Acid", Corrosion, Vol. 42, No. 11, p. 633 (1986).1 (455k)
- D. C. Silverman, "Rotating Cylinder Electrode - Geometry Relationships For Prediction of Velocity Sensitive Corrosion", Corrosion, Vol. 44, No. 1, p. 42 (1988).1 (521k)
- D. C. Silverman, "Rotating Cylinder Electrode - An Approach for Predicting Velocity Sensitive Corrosion", in Flow-Induced Corrosion: Fundamental Studies and Industrial Experience (K. J. Kennelley, R. H. Hausler, and D. C. Silverman, ed.), p. 20-1, NACE, Houston, Texas, 1991.
- D. C. Silverman, "Electrochemical Techniques - Simple Tests for Complex Predictions in the Chemical Process Industries", Corrosion Reviews, Vol. 10, No. 1-2, p. 31 (1992).
- Chairman of NACE Task Group On Fluid Velocity Accelerated Corrosion that developed the report entitled "State-of-the-Art Report on Controlled-Flow Laboratory Corrosion Tests", December, 1995.
- D. C. Silverman, "Technical Note: On Estimating Dynamic Conditions in Rotating Cylinder Electrode", Corrosion, Vol.55, No. 12, p. 1115, 1999.1 (270k)
- D. C. Silverman, "Simplified Equation for Simulating Velocity-Sensitive Corrosion in the Rotating Cylinder Electrode at Higher Reynolds Numbers" Corrosion, Vol. 59, No. 3, p. 207 2003.1 (327k)
- D. C. Silverman, "Practical Corrosion Prediction Using Electrochemical Techniques", chapter 68 in Uhlig Corrosion Handbook, Second Edition, R. W. Revie, editor, p. 1179, John Wiley and Sons, NY, 2000.(1800k)
- D. C. Silverman, "The Rotating Cylinder Electrode for Examining Velocity-Sensitive Corrosion - A Review", Corrosion, Vol.60, No.11, p. 1003, 2004.1 (1560k)
- D. C. Silverman, "Conditions for Similarity of Mass-Transfer Coefficients and Fluid Shear Stresses Between the Rotating Cylinder Electrode and Pipe", Corrosion, Vol.61, No.6, p. 515, 2005.1 (403k)
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Practical and rapid corrosion prediction using Electrochemical Impedance Spectroscopy
- D. C. Silverman, "Primer on AC Impedance Technique", in Electrochemical Techniques for Corrosion Engineering, R. Baboian, ed., p. 73, NACE, Houston, 1987.2 (369k)
- D. C. Silverman and J. E. Carrico, "Electrochemical Impedance Technique - A Practical Tool For Corrosion Prediction", Corrosion, Vol. 44, No. 5, p. 280 (1988).1 (516k)
- D. C. Silverman, "Corrosion Rate Estimation From Pseudo-Inductive Electrochemical Impedance Response", Corrosion, Vol. 45, No. 10, p. 824 (1989).1 (438k)
- D. C. Silverman, "Simple Models/Practical Answers Using the Electrochemical Impedance Technique", in Silver Anniversary Symposium on Electrochemical Testing and Evaluation (R. Baboian and S. W. Dean, ed.), ASTM STP 1000, p. 379, ASTM, Philadelphia, PA, 1990.
- D. C. Silverman, "Rapid Corrosion Screening in Poorly Defined Systems by Electrochemical Impedance Technique", Corrosion, Vol. 46, No. 7, p. 589 (1990).1 (568k)
- D. C. Silverman, "On Ambiguities In Modeling Electrochemical Impedance Spectra Using Circuit Analogues", Corrosion, Vol. 47, No. 2, p. 87 1991.1 (173k)
- D. C. Silverman, "Electrochemical Techniques - Simple Tests for Complex Predictions in the Chemical Process Industries", Corrosion Reviews, Vol. 10, No. 1-2, p. 31 (1992).
- D. C. Silverman, "Corrosion Prediction from Circuit Models - Application to Evaluation of Corrosion Inhibitors", in Electrochemical Impedance: Analysis and Interpretation (J. R. Scully, D. C. Silverman, and M. W. Kendig, ed.), ASTM STP 1188, p. 192, American Society for Testing and Materials, Philadelphia, PA, 1993.
- D. C. Silverman, "Corrosion Prediction in Complex Environments Using Electrochemical Impedance Technique", Electrochimica Acta, Vol. 38, No. 14, p. 2075 (1993).1 (195k)
- D. C. Silverman, "Corrosion Prediction from Accelerated Tests in the Chemical Process Industries", in, Application of Accelerated Corrosion Tests to Service Life Prediction of Materials (G. Cragnolino and N. Sridhar, ed), p. 42, ASTM STP 1194, American Society for Testing and Materials, Philadelphia, PA, 1994.
- D. C. Silverman, "Practical Corrosion Prediction Using Electrochemical Techniques", chapter 68 in Uhlig Corrosion Handbook, Second Edition, R. W. Revie, editor, p. 1179, John Wiley and Sons, NY, 2000.(1800k)
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Practical and rapid corrosion prediction using DC electrochemical techniques
- R. E. McGuire and D. C. Silverman, "Complementary Use of Laboratory and Plant Tests to Solve Complex Chemical Plant Corrosion Problems", Corrosion, Vol.47, No. 11, p. 894 (1991).1 (497k)
- D. C. Silverman, "Electrochemical Techniques - Simple Tests for Complex Predictions in the Chemical Process Industries", Corrosion Reviews, Vol. 10, No. 1-2, p. 31 (1992).
- D. C. Silverman and E. M. Rosen, "Corrosion Prediction from Polarization Scans Using an Artificial Neural Network Integrated with an Expert System", Corrosion, Vol.48, No. 9, p. 734 (1992).1 (774k)
- J. A. Beavers, N. G. Thompson, and D. C. Silverman, "Corrosion Engineering Applications of Electrochemical Techniques: Laboratory Testing", Paper #348, CORROSION/93, New Orleans, LA, 1993.
- D. C. Silverman, "Corrosion Prediction from Accelerated Tests in the Chemical Process Industries", in, Application of Accelerated Corrosion Tests to Service Life Prediction of Materials (G. Cragnolino and N. Sridhar, ed), p. 42, ASTM STP 1194, American Society for Testing and Materials, Philadelphia, PA, 1994.
- D. C. Silverman, "Measuring Corrosion Rates in Drinking Water by Linear Polarization - Assumptions and Watch-outs", Proceedings of the 1995 Water Quality Technology Conference (American Water Works Association), p. 2435, New Orleans, published, 1996.
- D. C. Silverman, "Tutorial on Cyclic Potentiodynamic Polarization Technique", Paper 299, CORROSION/98, San Diego, CA, 1998.
- D. C. Silverman, "Practical Corrosion Prediction Using Electrochemical Techniques", chapter 68 in Uhlig Corrosion Handbook, Second Edition, R. W. Revie, editor, p. 1179, John Wiley and Sons, NY, 2000.(1800k)
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Practical Applications of Artificial Neural Networks and Expert Systems to Corrosion
- D. C. Silverman and E. M. Rosen, "Corrosion Prediction from Polarization Scans Using an Artificial Neural Network Integrated with an Expert System", Corrosion, Vol.48, No. 9, p. 734 (1992).1 (774k)
- D. C. Silverman, "Artificial Neural Network to Predict Degradation of Non-Metallic Lining Materials from Laboratory Tests", Corrosion, Vol. 50, No. 6, p. 411 (1994).1 (513k)
- D. C. Silverman, "Corrosion Prediction from Laboratory Tests Using Artificial Neural Networks", Paper #048, 12th International Corrosion Congress, Houston, TX, September, 1993.
- A. L. Silverman and D. C. Silverman, "Easily Accessible Intelligent Tools on the Internet", Paper 05060, CORROSION/2005, Houston TX, 20051 (596k) Presentation Slides: (195k)
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Practical corrosion prediction in chemical plant waste streams
- D. C. Silverman, "Corrosion Rate Estimation From Pseudo-Inductive Electrochemical Impedance Response", Corrosion, Vol. 45, No. 10, p. 824 (1989).1 (438k)
- D. C. Silverman, "Rapid Corrosion Screening in Poorly Defined Systems by Electrochemical Impedance Technique", Corrosion, Vol. 46, No. 7, p. 589 (1990).1 (568k)
- R. E. McGuire and D. C. Silverman, "Complementary Use of Laboratory and Plant Tests to Solve Complex Chemical Plant Corrosion Problems", Corrosion, Vol.47, No. 11, p. 894 (1991).1 (497k)
- D. C. Silverman, "Electrochemical Techniques - Simple Tests for Complex Predictions in the Chemical Process Industries", Corrosion Reviews, Vol. 10, No. 1-2, p. 31 (1992).
- D. C. Silverman, "Corrosion Prediction in Complex Environments Using Electrochemical Impedance Technique", Electrochimica Acta, Vol. 38, No. 14, p. 2075 (1993).1 (195k)
- D. C. Silverman, "Practical Corrosion Prediction Using Electrochemical Techniques", chapter 68 in Uhlig Corrosion Handbook, Second Edition, R. W. Revie, editor, p. 1179, John Wiley and Sons, NY, 2000.(1800k)
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Enhanced prediction of performance of elastomers and other non-metallic materials
- D. C. Silverman and E. M. Rosen, "Sorption/Diffusion Estimation in Non-Metallics Using Fick's Laws", Corrosion, Vol. 46, No. 11, p. 945 (1990).1 (449k)
- D. C. Silverman, "Artificial Neural Network to Predict Degradation of Non-Metallic Lining Materials from Laboratory Tests", Corrosion, Vol. 50, No. 6, p. 411 (1994).1 (513k)
- Chairman of NACE Task Group on Testing of Non-Metallic Materials that developed the document "Standard Test Method on Chemical Resistance of Polymeric Materials by Periodic Evaluation", March, 1996.
- D. C. Silverman,"Introduction to Environmental Performance of Nonmetallic Materials, ASM Handbook, Vol.13B, ASM International, Materials Park, Ohio, 2005.
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Corrosion inhibitor development and evaluation
- D. C. Silverman and D. J. Kalota, "Process for Corrosion Inhibition of Ferrous Metals", US Patent 4,971,724, November 20, 1990. (977k)
- R. E. McGuire and D. C. Silverman, "Complementary Use of Laboratory and Plant Tests to Solve Complex Chemical Plant Corrosion Problems", Corrosion, Vol.47, No. 11, p. 894 (1991).1 (497k)
- D. C. Silverman, "Electrochemical Techniques - Simple Tests for Complex Predictions in the Chemical Process Industries", Corrosion Reviews, Vol. 10, No. 1-2, p. 31 (1992).
- D. C. Silverman, "Corrosion Prediction from Circuit Models - Application to Evaluation of Corrosion Inhibitors", in Electrochemical Impedance: Analysis and Interpretation (J. R. Scully, D. C. Silverman, and M. W. Kendig, ed.), ASTM STP 1188, p. 192, American Society for Testing and Materials, Philadelphia, PA, 1993.
- D. J. Kalota and D. C. Silverman, "Behavior of Aspartic Acid as a Corrosion Inhibitor for Steel", Corrosion, Vol. 50, No. 2, p. 138 (1994).1 (438k)
- D. J. Kalota, F. S. Stover, and D. C. Silverman, "Effect of pH on Corrosion Inhibition of Steel in Polyaspartic Acid", Corrosion, Vol. 51, No. 11, p. 818 (1995).1 (499k)
- D. J. Kalota and D. C. Silverman, "Metal Cleaning Agent, U. S. Patent 5,443,651, August 22, 1995. (541k)
- D. J. Kalota and D. C. Silverman, "Compositions for Corrosion Inhibition of Ferrous Metals", U. S. Patent 6200499, March 13, 2001. (990k)
- D. C. Silverman and T. K. Hirzel, "On Divergent Effects of N-Acylglutamates on Corrosion of Aluminum and Magnesium Alloys", Corrosion, Vol. 58, No. 2. p. 99, 2002.1 (226k)
- D. J. Kalota, Y. Chou, and D. C. Silverman, "Corrosion Inhibiting Compositions", US Patent 6,238,621 B1, May 29, 2001 (461k)
- D. C. Silverman, "A Perspective on Generating and Handling Corrosion Inhibition Related Data", Corrosion, Vol. 60, No. 1, p. 3, (2004).1 (153k)
- D. C. Silverman and A. L. Silverman, "Potential-pH (Pourbaix) Diagrams as Aids for Screening Corrosion Inhibitors and Sequestering Agents", Paper 07616, CORROSION/2007, Nashville, TN, 20071 (2396k) Presentation Slides: (321k)
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Advanced coating system development and evaluation/Conducting polymers
- D. C. Silverman, "Discussion of 'The Corrosion Of Nickel 270 In Phosphate Containing Solutions'", Corrosion, Vol. 41, No. 4, p. 244 (1985).1 (120k)
- D. C. Silverman, J. A. Lefelar, and P. J. Kinlen, "Metals Coated with Protective Coatings of Annealed Perfluorinated Cation-Exchange Polymers and Method for Making Same", US Patent 5,069,974, December 3, 1991. (1290k)
- P. J. Kinlen and D. C. Silverman, "Annealed Perfluorinated Cation Exchange Polymers for Corrosion Resistant Coatings", Journal of the Electrochemical Society, Vol. 140, No. 11, p. 3140 (1993).
- P. J. Kinlen, D. C. Silverman, C. R. Jeffreys, "Corrosion Protection Using Polyaniline Coating Formulations", Synthetic Metals, Vol 85 (1-3), p. 1327 (1997).
- P. J. Kinlen, C. R. Jeffreys, D. C. Silverman, "Corrosion Protection Using Polyaniline Coating Formulations", Pitture Vernici Eur., Vol. 73, No. 17, p. 47-48, 53, (1997).
- P. J. Kinlen, D. C. Silverman, J. C. Hardiman, "Corrosion Inhibiting Compositions", U. S. Patent 5,532,025, July 2, 1996. (785k)
- P. J. Kinlen, D. C. Silverman, J. C. Hardiman, Corrosion Inhibiting Multilayer Coating, U. S. Patent 6,015,613, January, 18, 2000. (641k)
- P. J. Kinlen, Y. Ding, and D. C. Silverman, "Corrosion Protection of Mild Steel Using Sulfonic and Phosphonic Acid Doped Polyanilines", Corrosion, Vol. 58, No. 6, p. 490, 2002.1 (687k)
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Practical corrosion prediction using potential-pH (Pourbaix) diagrams
- D. C. Silverman, "Revised EMF-pH Diagram For Nickel", Corrosion, Vol. 37, No 9, p. 546 (1981).1 (161k)
- D. C. Silverman, "Presence Of Solid Fe(OH)2 In EMF-pH Diagram For Iron", Corrosion, Vol. 38, No. 8, p. 453 (1982).1 (171k)
- D. C. Silverman, "Application Of EMF-pH Diagrams To Corrosion Prediction", Corrosion, Vol. 38, No. 10, p. 541 (1982).1 (557k)
- D. C. Silverman, "Absence of Cr(IV) In EMF-pH Diagram For Chromium", Corrosion, Vol. 39, No. 12, p. 488 (1983).1 (249k)
- D. C. Silverman, "Derivation and Application Of EMF-pH Diagrams", in Electrochemical Techniques for Corrosion Engineering, R. Baboian, ed., p. 117, NACE, Houston, 1987.2 (591k)
- D. C. Silverman, "Incorporation of Organic Complexing Agents on EMF-pH Diagrams", Corrosion, Vol. 44, No. 9, p. 606 (1988).1 (302k)
- D. C. Silverman, "Electrochemical Techniques - Simple Tests for Complex Predictions in the Chemical Process Industries", Corrosion Reviews, Vol. 10, No. 1-2, p. 31 (1992).
- D. J. Kalota and D. C. Silverman, "Behavior of Aspartic Acid as a Corrosion Inhibitor for Steel", Corrosion, Vol. 50, No. 2, p. 138 (1994).1 (438k)
- D. C. Silverman, "Practical Corrosion Prediction Using Electrochemical Techniques", chapter 68 in Uhlig Corrosion Handbook, Second Edition, R. W. Revie, editor, p. 1179, John Wiley and Sons, NY, 2000.(1800k)
- D. C. Silverman and A. L. Silverman, "Potential-pH (Pourbaix) Diagrams as Aids for Screening Corrosion Inhibitors and Sequestering Agents", Paper 07616, CORROSION/2007, Nashville, TN, 20071 (2396k) Presentation Slides: (321k)
- D. C. Silverman and A. L. Silverman, "Potential-pH (Pourbaix) Diagrams as Aids for Screening Corrosion Inhibitors and Sequestering Agents", Corrosion, Vol. 66, No. 5, p. 055003-1 (2010).1 (2584k)
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Other publications on prediction of uniform and localized corrosion
- D. C. Silverman, "Dimensionless Groups In The Modeling And Prediction Of Corrosion Processes", Corrosion, Vol. 41, No. 12, p. 679 (1985).1 (604k)
- D. C. Silverman and A. S. Krisher, "Design Considerations For Occluded Cell Corrosion Monitoring", in Corrosion Monitoring in Industrial Plants Using Nondestructive Testing and Electrochemical Methods, ed. G. C. Moran and P. Labine, ASTM STP 908, p. 472, 1986.
- D. C. Silverman, "Dimensionless Groups In The Modeling Of Corrosion Processes", in Corrosion Chemistry Within Pits, Crevices, and Cracks, A. Turnbull, ed., HMSO Publications Center, London, 1987.
- D. C. Silverman and R. B. Puyear, "Effects of Environmental Variables on Aqueous Corrosion", p. 37, Vol. 13, Metals Handbook, 9th Edition, ASM International, Metals Park, Ohio, 1987.
- R. A. Freeman and D. C. Silverman, "On Error Propagation in Coupon Immersion Testing", Corrosion, Vol. 48, No. 6, p. 463 (1992).1 (193k)
- D. C. Silverman, "Standardization of Electrochemical Corrosion Testing", ASTM Standardization News, May, 1993, p. 24.
- D. C. Silverman, "Types of Data", Manual on Corrosion Tests and Standards (R. Baboian, ed.) p. 40, American Society for Testing and Materials, 1995.
- J. R. Kearns, D. A. Eden, M. R. Yaffe, J. V. Fahey, D. L. Reichert, D. C. Silverman, "ASTM Standardization of Electrochemical Noise Measurement", ASTM STP 1277, p. 446 (1996).
- D. C. Silverman, "Corrosion Literature has Conflicting Definitions", Materials Performance, Vol. 38, No. 3, p. 77 (1999).3 (236k)
- R. L. Motard, X.D. Dai, B. Joseph (Chemical Engineering Department, Washington University, St. Louis), D. C. Silverman, "Corrosion Process Monitoring Using Wavelet Analysis", Ind. Eng. Chem. Research, Vol. 39, p. 1256 (2000).
- R. L. Motard, X.D. Dai, B. Joseph (Chemical Engineering Department, Washington University, St. Louis), D. C. Silverman, "Improved Discrimination of Electrochemical Noise Signals Using Wavelet Analysis", Corrosion, Vol. 57, No. 5, p. 394 (2001).1 (671k)
- D. C. Silverman, "Aqueous Corrosion", ASM Handbook, Vol. 13A, p. 190, ASM International, Materials Park, Ohio, 2003.
- D. C. Silverman, "A Perspective on Generating and Handling Corrosion Inhibition Related Data", Corrosion, Vol. 60, No. 1, p. 3, (2004).1 (153k)
- D. J. Kalota, Y. Chou, T. K. Hirzel, D. C. Silverman, J. S. Tau, and W. R. Cho, "Water Soluble Metal Working Fluids", U. S. Patent 6,706,670 B2, March 16, 2004. (1950k) Abstract: (61k)
- D. C. Silverman, "Types of Data", Manual on Corrosion Tests and Standards, 2nd Edition (R. Baboian, ed.) p. 59, American Society for Testing and Materials, 2005.
- D. C. Silverman and T. K. Hirzel, "Functional Fluid Compositions Containing Erosion Inhibitors", U.S. Patent Application No. US2005/0056809A1, March 17, 2005. (Anti-erosion additives for airplane hydraulic fluids.) (1830k) Abstract: (22k)
- D. C. Silverman and T. K. Hirzel, "Functional Fluid Compositions Containing Erosion Inhibitors", U.S. Patent No. 7255808, August 14, 2007. (Anti-erosion additives for airplane hydraulic fluids.) (2370k)
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1 © NACE International publication and year shown in citation above. All rights reserved. Displayed with permission from NACE International, Houston, TX (http://www.nace.org). Published in Corrosion, in the month and year shown in the citation above.
2 © NACE International 1987. All rights reserved. Displayed with permission from NACE International, Houston, TX. (http://www.nace.org). Published in Electrochemical Techniques for Corrosion Engineering, R. Baboian, ed., NACE, Houston, 1987.
3 © NACE International publication and year shown in citation above. All rights reserved. Displayed with permission from NACE International, Houston, TX (http://www.nace.org). Published in Materials Performance, in the month and year shown in the citation above.
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